[μ-2-Methyl-5-(methyl­sulfanylmeth­yl)aza­ferrocene]bis­­(penta­carbonyl­tungsten)

Kowalski, Konrad; White, Andrew J.P.

dc.contributor.author	Kowalski, Konrad
dc.contributor.author	White, Andrew J.P.
dc.date.accessioned	2022-02-12T16:57:06Z
dc.date.available	2022-02-12T16:57:06Z
dc.date.issued	2007
dc.identifier.issn	2056-9890
dc.identifier.uri	http://hdl.handle.net/11089/40631
dc.description	The title compound, [W2Fe(C5H5)(C7H10NS)(CO)10], was prepared by reaction of 5-methylsulfanylmethyl-2-methyl azaferrocene with photochemically generated [W(CO)5]·THF. The X-ray structural analysis showed the azaferrocenyl unit to have adopted a nearly eclipsed geometry. The geometries at the two tungsten centers are distorted octahedral.	pl_PL
dc.description.sponsorship	We acknowledge financial support from Imperial College London and the University of Łodz.	pl_PL
dc.language.iso	en	pl_PL
dc.publisher	International Union of Crystallography	pl_PL
dc.relation.ispartofseries	Acta Crystallographica Section E: Crystallographic Communications;63
dc.rights	Uznanie autorstwa 4.0 Międzynarodowe	*
dc.rights.uri	http://creativecommons.org/licenses/by/4.0/	*
dc.subject	Single-crystal X-ray study	pl_PL
dc.subject	T = 173 K	pl_PL
dc.subject	Mean σ(C–C) = 0.005 Å	pl_PL
dc.subject	R factor = 0.025	pl_PL
dc.subject	wR factor = 0.063	pl_PL
dc.subject	Data-to-parameter ratio = 25.5	pl_PL
dc.title	[μ-2-Methyl-5-(methylsulfanylmethyl)azaferrocene]bis(pentacarbonyltungsten)	pl_PL
dc.type	Article	pl_PL
dc.page.number	m392-m393	pl_PL
dc.contributor.authorAffiliation	Department of Organic Chemistry, University of Łódź, 90-136 Łódź, Narutowicza 68, Poland	pl_PL
dc.contributor.authorAffiliation	Department of Chemistry, Imperial College London, South Kensington, London SW 7AZ, England	pl_PL
dc.identifier.eissn	1600-5368
dc.references	Best, S. P., Clark, R. J. H., Deeming, A. J., McQueen, R. C. S., Powell, N. I., Acuna, C., Arce, A. J. & De Sanctis, Y. (1991). J. Chem. Soc. Dalton Trans. pp. 1111–1115.	pl_PL
dc.references	Bruker (1999). SHELXTL. Version 5.1. Bruker AXS Inc., Madison, Wisconsin, USA.	pl_PL
dc.references	Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887–897.	pl_PL
dc.references	Jerzykiewicz, L. B., Kowalski, K. & Zakrzewski, J. (2006). Acta Cryst. E62, m1832–m1834.	pl_PL
dc.references	Kowalski, K. & Zakrzewski, J. (2004). J. Organomet. Chem. 689, 1046–1049.	pl_PL
dc.references	Kowalski, K., Zakrzewski, J. & Jerzykiewicz, L. (2005a). J. Organomet. Chem. 690, 764–772.	pl_PL
dc.references	Kowalski, K., Zakrzewski, J. & Jerzykiewicz, L. (2005b). J. Organomet. Chem. 690, 1474–1477.	pl_PL
dc.references	Oxford Diffraction (2006). CrysAlis CCD and CrysAlis RED. Versions 1.171. Oxford Diffraction Ltd, Abingdon, Oxfordshire, England.	pl_PL
dc.references	Pyshnograeva, N. I., Setkina, V. N. & Kursanov, D. N. (1984). Izv. Akad. Nauk. SSSR Ser. Khim. pp. 2778–2780.	pl_PL
dc.references	Salo, E. V. & Guan, Z. (2003). Organometallics, 22, 5033–5046.	pl_PL
dc.references	Sheldrick, G. M. (1997). SHELXS97 and SHELXL97. University of Göttingen, Germany.	pl_PL
dc.references	Silver, J., Zakrzewski, J., Tosik, A. & Bukowska-Strzyzewska, M. (1997). J. Organomet. Chem. 540, 169–174.	pl_PL
dc.references	Watanabe, M. (2005). Macromol. Rapid Commun. 26, 34–39.	pl_PL
dc.references	Zakrzewski, J. & Giannotti, C. (1994). Trends Organomet. Chem. C49, 84–85.	pl_PL
dc.references	Zakrzewski, J. & Giannotti, C. (1995). Coord. Chem. Rev. 140, 167–187.	pl_PL
dc.contributor.authorEmail	kondor15@wp.pl	pl_PL
dc.identifier.doi	10.1107/S1600536806056121
dc.relation.volume	2	pl_PL
dc.discipline	nauki chemiczne	pl_PL