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[μ-2-Methyl-5-(methyl­sulfanylmeth­yl)aza­ferrocene]bis­­(penta­carbonyl­tungsten)

dc.contributor.authorKowalski, Konrad
dc.contributor.authorWhite, Andrew J.P.
dc.date.accessioned2022-02-12T16:57:06Z
dc.date.available2022-02-12T16:57:06Z
dc.date.issued2007
dc.identifier.issn2056-9890
dc.identifier.urihttp://hdl.handle.net/11089/40631
dc.descriptionThe title compound, [W2Fe(C5H5)(C7H10NS)(CO)10], was prepared by reaction of 5-methyl­sulfanylmethyl-2-methyl aza­ferrocene with photochemically generated [W(CO)5]·THF. The X-ray structural analysis showed the azaferrocenyl unit to have adopted a nearly eclipsed geometry. The geometries at the two tungsten centers are distorted octahedral.pl_PL
dc.description.sponsorshipWe acknowledge financial support from Imperial College London and the University of Łodz.pl_PL
dc.language.isoenpl_PL
dc.publisherInternational Union of Crystallographypl_PL
dc.relation.ispartofseriesActa Crystallographica Section E: Crystallographic Communications;63
dc.rightsUznanie autorstwa 4.0 Międzynarodowe*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectSingle-crystal X-ray studypl_PL
dc.subjectT = 173 Kpl_PL
dc.subjectMean σ(C–C) = 0.005 Åpl_PL
dc.subjectR factor = 0.025pl_PL
dc.subjectwR factor = 0.063pl_PL
dc.subjectData-to-parameter ratio = 25.5pl_PL
dc.title[μ-2-Methyl-5-(methyl­sulfanylmeth­yl)aza­ferrocene]bis­­(penta­carbonyl­tungsten)pl_PL
dc.typeArticlepl_PL
dc.page.numberm392-m393pl_PL
dc.contributor.authorAffiliationDepartment of Organic Chemistry, University of Łódź, 90-136 Łódź, Narutowicza 68, Polandpl_PL
dc.contributor.authorAffiliationDepartment of Chemistry, Imperial College London, South Kensington, London SW 7AZ, Englandpl_PL
dc.identifier.eissn1600-5368
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dc.contributor.authorEmailkondor15@wp.plpl_PL
dc.identifier.doi10.1107/S1600536806056121
dc.relation.volume2pl_PL
dc.disciplinenauki chemicznepl_PL


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Uznanie autorstwa 4.0 Międzynarodowe
Except where otherwise noted, this item's license is described as Uznanie autorstwa 4.0 Międzynarodowe