dc.contributor.author | Jankowiak, Aleksandra | |
dc.contributor.author | Pociecha, Damian | |
dc.contributor.author | Szczytko, Jacek | |
dc.contributor.author | Monobe, Hirosato | |
dc.contributor.author | Kaszyński, Piotr | |
dc.date.accessioned | 2016-03-31T09:30:55Z | |
dc.date.available | 2016-03-31T09:30:55Z | |
dc.date.issued | 2013 | |
dc.identifier.uri | http://hdl.handle.net/11089/17591 | |
dc.description.abstract | A series of six 6-oxoverdazyl (1[10]) substituted with a total of three 3,4,5-tri(decyloxy)phenyl and/or 3,4,5-tri(decylsulfanyl)phenyl groups was investigated by thermal, XRD, spectroscopic, magnetic and photovoltaic methods. The compounds exhibit columnar hexagonal (1[10]c, Colh), columnar hexagonal ordered (1[10]b, Colh(o)), columnar hexagonal 3D (1[10]a, 1[10]e and 1[10]f, Colh(3D)) or a sequence of two phases (1[10]b, Colh–Colh(3D)). The mesophase structure and stability and also thermochromism were investigated as a function of the number and distribution of decyloxy and decylsulfanyl substituents in the molecule. Thermal analysis demonstrated that the presence of the 3,4,5-tri(decyloxy)phenyl substituent in the C(3) position increases the phase stability. Spectroscopic analysis showed that only all-decyloxy derivative 1[10]b exhibits a hypsochromic shift upon Colh(o) formation, while all other compounds in the series show a modest bathochromic shift in the columnar phase relative to the isotropic phase. Magnetization investigation of 1[10]d demonstrated the paramagnetic behavior of isolated spins in isotropic and columnar phases. Negligible photocurrent was detected for 1[10]d in the columnar phase. | pl_PL |
dc.description.sponsorship | This work was supported by NSF grants (CHEM-1214104). We
thank Prof. Andrzej Twardowski for funding SQUID
measurements | pl_PL |
dc.language.iso | en | pl_PL |
dc.publisher | The Royal Society of Chemistry | pl_PL |
dc.relation.ispartofseries | Journal of Materials Chemistry C;2 | |
dc.rights | Uznanie autorstwa 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
dc.title | Liquid crystalline radicals: discotic behavior of unsymmetrical derivatives of 1,3,5-triphenyl-6-oxoverdazyl | pl_PL |
dc.type | Article | pl_PL |
dc.page.number | 319-324 | pl_PL |
dc.contributor.authorAffiliation | Vanderbilt Universit, Department of Chemistry | pl_PL |
dc.contributor.authorAffiliation | University of Warsaw, Department of Chemistry | pl_PL |
dc.contributor.authorAffiliation | University of Warsaw, Faculty of Physics | pl_PL |
dc.contributor.authorAffiliation | AIST Kansai Centre, National Institute of Advanced Industrial Science and Technology | pl_PL |
dc.contributor.authorAffiliation | University of Łódź, Faculty of Chemistry | pl_PL |
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dc.contributor.authorEmail | piotr.kaszynski@vanderbilt.edu | pl_PL |
dc.identifier.doi | 10.1039/C3TC31984A | |