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Asymmetric Friedel–Crafts Alkylation of Indoles Catalyzed by Chiral Aziridine-Phosphines

dc.contributor.authorBuchcic, Aleksandra
dc.contributor.authorZawisza, Anna
dc.contributor.authorLeśniak, Stanisław
dc.contributor.authorRachwalski, Michał
dc.date.accessioned2021-10-26T08:30:09Z
dc.date.available2021-10-26T08:30:09Z
dc.date.issued2020
dc.identifier.citationBuchcic, A.; Zawisza, A.; Leśniak, S.; Rachwalski, M. Asymmetric Friedel–Crafts Alkylation of Indoles Catalyzed by Chiral Aziridine-Phosphines. Catalysts 2020, 10, 971. https://doi.org/10.3390/catal10090971pl_PL
dc.identifier.issn2073-4344
dc.identifier.urihttp://hdl.handle.net/11089/39553
dc.description.abstractOver the course of the present studies, a series of optically pure phosphines functionalized by chiral aziridines was synthesized in reasonable/good chemical yields. Their catalytic activity was checked in the enantioselective Friedel–Crafts alkylation of indoles by β-nitrostyrene in the presence of a copper(I) trifluoromethanesulfonate benzene complex. The corresponding Friedel–Crafts products were achieved efficiently in terms of chemical yield and enantioselectivity (up to 85% in some cases).pl_PL
dc.description.sponsorshipThis research was funded by the National Science Centre (NCN) (Grant No. 2016/21/B/ST5/00421 for M.R.).pl_PL
dc.language.isoenpl_PL
dc.publisherMDPIpl_PL
dc.relation.ispartofseriesCatalysts;10(9)
dc.rightsUznanie autorstwa 4.0 Międzynarodowe*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectasymmetric transformationspl_PL
dc.subjectchiral aziridinyl-phosphinespl_PL
dc.subjectenantioselective Friedel–Crafts alkylationpl_PL
dc.subjectstereoselectivitypl_PL
dc.titleAsymmetric Friedel–Crafts Alkylation of Indoles Catalyzed by Chiral Aziridine-Phosphinespl_PL
dc.typeArticlepl_PL
dc.page.number10pl_PL
dc.contributor.authorAffiliationDepartment of Organic and Applied Chemistry, University of Łódź, Tamka 12, 91-403 Łódź, Polandpl_PL
dc.contributor.authorAffiliationDepartment of Organic and Applied Chemistry, University of Łódź, Tamka 12, 91-403 Łódź, Polandpl_PL
dc.contributor.authorAffiliationDepartment of Organic and Applied Chemistry, University of Łódź, Tamka 12, 91-403 Łódź, Polandpl_PL
dc.contributor.authorAffiliationDepartment of Organic and Applied Chemistry, University of Łódź, Tamka 12, 91-403 Łódź, Polandpl_PL
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dc.identifier.doi10.3390/catal10090971
dc.relation.volume971pl_PL
dc.disciplinenauki chemicznepl_PL


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