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Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S˙
(The Royal Society of Chemistry, 2013-08-15)
The atmospherically highly relevant methylsulfinyl radical CH3(O)S˙ was generated thermally under flash pyrolysis conditions and isolated in Ar matrices at 10 K; the allyl radical is a byproduct. CH3(O)S˙ and its D3- and ...