Artykuły naukowe | Articles: Recent submissions
Now showing items 61-80 of 91
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The Influence of Protonation on the Electroreduction of Bi (III) Ions in Chlorates (VII) Solutions of Different Water Activity
(Springer, 2015-02-24)We examined the electroreduction of Bi (III) ions in chlorate (VII) solutions under varied protonation conditions of the depolariser using voltammetric and impedance methods. The results of the kinetic parameter correlation ... -
Effects of Constant Magnetic Field on Electrodeposition of Co-W-Cu Alloy
(Electrochemical Science Group, 2015-03-23)The paper presents a study of the effect of constant magnetic field (CMF) on the basic processes of Co-W-Cu alloys electrodeposition. The alloys electrodeposited in the presence of CMF were more homogeneous and smooth ... -
Synthesis and (spectro)electrochemistry of mixedvalent diferrocenyl–dihydrothiopyran derivatives
(Royal Society of Chemistry, 2015-02-20)Three novel diferrocenyl complexes were prepared and characterised. 2,2-Diferrocenyl-4,5-dimethyl- 3,6-dihydro-2H-thiopyran (1, sulphide) was accessible by the hetero-Diels–Alder reaction of diferrocenyl thioketone with ... -
On the strong difference in reactivity of acyclic and cyclic diazodiketones with thioketones: experimental results and quantum-chemical interpretation
(Beilstein-Institut zur Förderung der Chemischen Wissenschaften, 2015-04-20)The 1,3-dipolar cycloaddition of acyclic 2-diazo-1,3-dicarbonyl compounds (DDC) and thioketones preferably occurs with Z,Econformers and leads to the formation of transient thiocarbonyl ylides in two stages. The ... -
Interactions of the Gasotransmitters Contribute to Microvascular Tone (Dys)regulation in the Preterm Neonate
(Public Library Of Science, 2015-03-25)Background & Aims Hydrogen sulphide (H2S), nitric oxide (NO), and carbon monoxide (CO) are involved in transitional microvascular tone dysregulation in the preterm infant; however there is conflicting evidence on the ... -
Dendritic glycopolymers based on dendritic polyamine scaffolds: view on their synthetic approaches, characteristics and potential for biomedical applications
(The Royal Society of Chemistry, 2014-12-18)In this review we highlight the potential for biomedical applications of dendritic glycopolymers based on polyamine scaffolds. The complex interplay of the molecular characteristics of the dendritic architectures and their ... -
Why 1,2‑quinone derivatives are more stable than their 2,3‑analogues?
(Springer Berlin Heidelberg, 2015-02-25)In this work, we have studied the relative stability of 1,2- and 2,3-quinones. While 1,2-quinones have a closed-shell singlet ground state, the ground state for the studied 2,3-isomers is open-shell singlet, except ... -
Application of a Graphene Oxide–Carbon Paste Electrode for the Determination of Lead in Rainbow Trout from Central Europe
(Springer, 2014-06-22)In the presented study, the content of lead in rainbow trout (Oncorhynchus mykiss) samples was examined. Rainbow trout were purchased in Prague (Czech Republic), Lodz (Poland) and Bratislava (Slovakia) from local fish shops ... -
Dialkyldithiophosphate Acids (HDDPs) as Effective Lubricants of Sol–Gel Titania Coatings in Technical Dry Friction Conditions
(Springer, 2012)The goal of this study was the investigation of the effectiveness of dialkyldithiophosphate acids (HDDPs) films in improving the tribological properties of thin, sol– gel derived titania coatings. Amorphous, anatase, ... -
Phase Behavior and Heat Capacity of {DPnP + Water} Mixtures at the Temperature Range of 273.15–338.15 K
(Hindawi Publishing Corporation, 2015)The differential scanning calorimetry method (DSC) was used to examine the miscibility in the {dipropylene glycol propyl ether (DPnP) + water} system. -
Who Receives Home-Based Perinatal Palliative Care: Experience from Poland
(Hindawi Publishing Corporation, 2013)The current literature suggests that perinatal palliative care (PPC) programs should be comprehensive, initiated early, and integrative. So far there have been very few publications on the subject of home-based PC of ... -
Association between the c.*229C>T polymorphism of the topoisomerase IIb binding protein 1 (TopBP1) gene and breast cancer
(Springer, 2013)Topoisomerase IIb binding protein 1 (TopBP1) is involved in cell survival, DNA replication, DNA damage repair and cell cycle checkpoint control. The biological function of TopBP1 and its close relation with BRCA1 prompted ... -
The Oxidative Stress May be Induced by the Elevated Homocysteine in Schizophrenic Patients
(Springer, 2012)The mechanisms of oxidative stress in schizophrenic patients are not fully understood. In the present study, we investigated the effect of elevated level of homocysteine (Hcys) on some parameters of oxidative stress, namely ... -
The Effects of Cocaine on Different Redox Forms of Cysteine and Homocysteine, and on Labile, Reduced Sulfur in the Rat Plasma Following Active versus Passive Drug Injections
(Springer Verlag, 2013)The aim of the present studies was to evaluate cocaine-induced changes in the concentrations of different redox forms of cysteine (Cys) and homocysteine (Hcy), and products of anaerobic Cys metabolism, i.e., labile, reduced ... -
Treatment of chronic hemodialysis patients with low-dose fenofibrate effectively reduces plasma lipids and affects plasma redox status
(BioMed Central, 2012)Dyslipidemia is common in chronic hemodialysis patients and its underlying mechanism is complex. Hemodialysis causes an imbalance between antioxidants and production of reactive oxygen species, which induces the oxidative ... -
Superhydrophobic Surface by Replication of Laser Micromachined Pattern in Epoxy/Alumina Nanoparticle Composite
(Hindawi Publishing Corporation, 2014-04-24)Superhydrophobic surfaces were obtained by superposition of microstructure—defined by replication of laser micromachined masters, with nanostructure—created by durable epoxy/γ-Al₂O₃ nanoparticle composite, used for ... -
Surface area or diameter – which factor really determines the antibacterial activity of silver nanoparticles grown on TiO₂ coatings?
(The Royal Society of Chemistry, 2014)Titanium dioxide coatings were prepared on Si wafers using the sol–gel method. Four different types of coatings with silver nanoparticles (AgNPs) were synthesized. The diameter and surface density of AgNPs were conditioned ... -
Studies of the complexation behavior of tetramorpholinylo-PNP-lariat ether with Ag(I), Ca(II), Cd(II), Cu(II) and Pb(II) using Electrospray Ionization Mass Spectrometry
(The Royal Society of ChemistryK. Vekey, J. Chromatogr. A, 2001, 921, 227–236, 2014-12-17)In this publication the cationic metal complexes of tetramorpholinylo-PNP-lariat ether have been studied using electrospray ionization mass spectrometry (ESI-MS). The tandem mass spectra (MS/MS) of these complexes have ... -
Efficient synthesis of pyrene-1-carbothioamides and carboxamides. Tunable solid-state fluorescence of pyrene-1-carboxamides
(The Royal Society of Chemistry, 2014-10-23)Pyrene reacts with potassium thiocyanate and organic isothiocyanates in the presence of trifluoromethanesulfonic acid to afford primary and secondary pyrene-1-carbothioamides in high yields. These compounds were efficiently ... -
A new class of pyrenyl solid-state emitters: 1-pyrenyl ynones. Synthesis via the Friedel–Crafts route, molecular and electronic structure and photophysical properties
(The Royal Society of Chemistry, 2014-06-15)Friedel–Crafts acylation of pyrene with alkynoic acids in the presence of trifluoroacetic anhydride and triflic acid constitutes a direct and efficient route to 1-pyrenyl ynones. These compounds in chloroform solution emit ...