Partial Molar Volumes of 15-Crown-5 Ether in Mixtures of N,N-Dimethylformamide with Water
| dc.contributor.author | Tyczyńska, Magdalena | |
| dc.contributor.author | Jóźwiak, Małgorzata | |
| dc.date.accessioned | 2016-03-23T10:56:03Z | |
| dc.date.available | 2016-03-23T10:56:03Z | |
| dc.date.issued | 2014 | |
| dc.identifier.issn | 0095-9782 | |
| dc.identifier.uri | http://hdl.handle.net/11089/17524 | |
| dc.description.abstract | The density of 15-crown-5 ether (15C5) solutions in the mixtures of N,N-dimethylformamide (DMF) and water (H_2O) was measured within the temperature range 293.15–308.15 K using an Anton Paar oscillatory U-tube densimeter. The results were used to calculate the apparent molar volumes (V Φ ) of 15C5 in the mixtures of DMF + H_2O over the whole concentration range. Using the apparent molar volumes and Redlich and Mayer equation, the standard partial molar volumes of 15-crown-5 were calculated at infinite dilution (V_m^o). The limiting apparent molar expansibilities (α) were also calculated. The data are discussed from the point of view of the effect of concentration changes on interactions in solution. | pl_PL |
| dc.description.sponsorship | This study was supported by ZPORR, Project: Post-graduate students—Regional Investment in Young Scientists D-RIM II edition co-financed by the European Union from the European Social Fund within the Operational Program Human Capital (Human—best investment), which is gratefully acknowledged. The authors would like to thank Prof. Adam Bald for discussion and Prof. W. Earle Waghorne for useful suggestions. | pl_PL |
| dc.language.iso | en | pl_PL |
| dc.publisher | Springer US | pl_PL |
| dc.relation.ispartofseries | Journal of Solution Chemistry;2 | |
| dc.rights | Uznanie autorstwa 3.0 Polska | * |
| dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
| dc.subject | N,N-Dimethylformamide–water mixture | pl_PL |
| dc.subject | 15-Crown-5 | pl_PL |
| dc.subject | Density | pl_PL |
| dc.subject | Partial molar volume | pl_PL |
| dc.subject | Hydrophobic hydration | pl_PL |
| dc.title | Partial Molar Volumes of 15-Crown-5 Ether in Mixtures of N,N-Dimethylformamide with Water | pl_PL |
| dc.type | Article | pl_PL |
| dc.page.number | 388-403 | pl_PL |
| dc.contributor.authorAffiliation | University of Lodz, Department of Physical Chemistry | pl_PL |
| dc.identifier.eissn | 1572-8927 | |
| dc.references | Illoukhani, H., Khanlarzadeh, K.: Densities, viscosities, and refractive indices for binary and ternary mixtures of N,N-dimethylacetamide (1) + 2-methylbutan-2-ol (2) + ethyl acetate (3) at 298.15 K for the liquid region and at ambient pressure. J. Chem. Eng. Data 51, 1226–1231 (2006) | pl_PL |
| dc.references | Cwiklinska, A., Kinart, C.M.: Thermodynamic and physicochemical properties of binary mixtures of nitromethane with 2-methoxyethanol + 2-butoxyethanol systems at T = (293.15, 298.15, 303.15, 308.15, and 313.15) K. J. Chem. Thermodyn. 43, 420–429 (2011) | pl_PL |
| dc.references | Kinart, C.M., Maj, M., Cwiklinska, A., Kinart, W.J.: Densities, viscosities and relative permittivities of some n-alkoxyethanols with sulfolane at T = 303.15 K. J. Mol. Liq. 139, 1–7 (2008) | pl_PL |
| dc.references | Dubey, G.P., Kumar, K.: Studies of thermophysical properties of binary liquid mixtures of amine and alcohols at various temperatures. J. Chem. Thermodyn. 50, 7–14 (2012) | pl_PL |
| dc.references | Chauhan, S., Chaudhary, P., Sharma, K., Kumar, K.K.: Temperature-dependent volumetric and viscometric properties of amino acids in aqueous solutions of an antibiotic drug. Chem. Pap. 67, 1442–1452 (2013) | pl_PL |
| dc.references | Singh, R., Yasmin, M., Agarwal, H., Shukla, V.K., Gupta, M., Shukla, J.P.: Study of molecular interactions in binary mixtures of formamide with 2-methoxyethanol and 2-ethoxyethanol at varying temperatures. Phys. Chem. Liq. 51, 606–620 (2013) | pl_PL |
| dc.references | Ghazoyan, H.H., Markarian, S.A.: Densities and thermochemical properties of dimethylsulfone in dimethylsulfoxide and dimethylsulfoxide/water equimolar mixture. J. Mol. Liq. 183, 85–88 (2013) | pl_PL |
| dc.references | Qi, Z., Soka, M.: Dynamic properties of individual water molecules in a hydrophobic pore lined with acyl chains: a molecular dynamics study. Biophys. Chem. 71, 35–50 (1998) | pl_PL |
| dc.references | García, B., Alcalde, R., Aparicio, S., Leal, J.M., Matos, J.S.: Solute–solvent interactions in the (N,N-dimethylformamide + N-methyloformamide + water) ternary system at 298.15 K. Phys. Chem. Chem. Phys. 3, 2866–2871 (2001) | pl_PL |
| dc.references | Rouw, A., Somsen, G.: Solvation and hydrophobic hydration of alkyl-substituted ureas and amides in N,N-dimethylformamide + water mixtures. J. Chem. Soc. Faraday Trans. 1 78, 3397–3408 (1982) | pl_PL |
| dc.references | Zielkiewicz, J.: Preferential solvation of N-methylformamide, N,N-dimethylformamide and N-methylacetamide by water and alcohols in the binary and ternary mixtures. Phys. Chem. Chem. Phys. 2, 2925–2932 (2000) | pl_PL |
| dc.references | Gokel, G.W., Leevy, W.M., Weber, M.E.: Crown ethers: sensors for ions and molecular scaffolds for materials and biological models. Chem. Rev. 104, 2723–2750 (2004) | pl_PL |
| dc.references | Takeda, Y., Tanaka, M., Yamada, H., Katsuta, S.: Stabilities and transfer activity coefficients from water to polar nonaqueous solvents of benzo-15-crown-5- and 15-crown-5-alkali metal ion complexes. J. Coord. Chem. 55, 459–468 (2002) | pl_PL |
| dc.references | Patil, J.K., Pawar, R.B., Gokavi, G.S.: Studies of partial molar volumes of 18-crown-6 in water at 25 °C. J. Mol. Liq. 75, 143–148 (1998) | pl_PL |
| dc.references | Usacheva, T.R., Kuzmina, I.A., Sharnin, V.A., Chernov, I.V., Matteoli, E.: Influence of the composition of aqueous dimethylsulfoxide solvent on thermodynamics of complexing between 18-crown-6-ether and d,l-alanine. Russ. J. Phys. Chem. A 86, 1064–1067 (2012) | pl_PL |
| dc.references | Usacheva, T.R., Sharnin, V.A., Matteoli, E.: Effect of solvation on the thermodynamics of the formation of molecular complexes of 18-crown-6 ether with glycine in water–dimethylsulfoxide solutions. Russ. J. Phys. Chem. A 11, 1898–1902 (2011) | pl_PL |
| dc.references | Rounaghi, G.H., Mohajeri, M., Soruri, F., Kakhki, R.M.: Solvent influence upon complex formation between dibenzo-18-crown-6 with the Y3+ metal cation in pure and binary mixed organic solvents. J. Chem. Eng. Data 56, 2836–2840 (2011) | pl_PL |
| dc.references | Takeda, Y., Kanazawa, M., Katsuta, S.: Thermodynamic study on transfer from water to polar nonaqueous solvents of 18-crown-6 and its 1:1 complexes with alkali metal ions. Anal. Sci. 16, 929–934 (2000) | pl_PL |
| dc.references | Patil, K.J., Dagade, D.H.: Studies of molecular interactions in aqueous and CCl4 solutions involving 18-crown-6 by application of Kirkwood–Buff theory. J. Chem. Thermodyn. 36, 677–682 (2004) | pl_PL |
| dc.references | Dagade, D.H., Shetake, P.K., Patil, K.J.: Thermodynamic studies of aqueous and CCl4 solutions of 15-crown-5 at 298.15 K: an application of McMillan–Mayer and Kirkwood–Buff theories of solutions. J. Phys. Chem. B 111, 7610–7619 (2009) | pl_PL |
| dc.references | Jóźwiak, M., Tyczyńska, M.: Volumetric properties of urea in the mixture of N,N-dimethylformamide with water. J. Chem. Eng. Data 57, 2067–2075 (2012) | pl_PL |
| dc.references | Chan, S.C., Valleau, J.P.: Ultrasonic study of hydrochloric acid association in N,N-dimethylformamide. Can. J. Chem. 46, 853–858 (1968) | pl_PL |
| dc.references | Schmulbach, C.D., Drago, R.S.: Molecular addition compounds of iodine. III. An infrared investigation of the interaction between dimethylacetamide and iodine. J. Am. Chem. Soc. 82, 4484–4487 (1960) | pl_PL |
| dc.references | Riddick, J.A., Bunger, W.B., Sakano, T.K.: Organic Solvents, Physical Properties and Methods of Purification, 4th edn. Wiley Interscience, New York (1986) | pl_PL |
| dc.references | Sharlin, P., Steinby, K., Domańska, U.: Volumetric properties of binary mixtures of N,N-dimethylformamide with water or water-d2 at temperatures from 277.13 to 318.15 K. J. Chem. Thermodyn. 34, 927–957 (2002) | pl_PL |
| dc.references | Berna-García, J.M., Guzmán-López, A., Cabrales-Torres, A., Estrada-Baltazar, A., Iglesias-Silva, G.A.: Densities and viscosities of (N,N-dimethylformamide + water) at atmospheric pressure from (283.15 to 353.15) K. J. Chem. Eng. Data 53, 1024–1027 (2008) | pl_PL |
| dc.references | Tôrres, R.B., Marchiore, A.C.M., Volpe, P.L.O.: Volumetric properties of binary mixtures of (water + organic solvents) at temperatures between T = 288.15 K and T = 303.15 K at p = 0.1 MPa. J. Chem. Thermodyn. 38, 526–541 (2006) | pl_PL |
| dc.references | Bakshi, M.S., Kaur, G.: Thermodynamic behavior of mixtures. 4. Mixtures of methanol with pyridine and N,N-dimethylformamide at 25 °C. J. Chem. Eng. Data 42, 298–300 (1997) | pl_PL |
| dc.references | Bendová, M., Rehák, K., Matous, J., Novak, J.P.: Liquid–liquid equilibrium and excess enthalpies in binary systems methylcyclohexane + methanol and methylcyclohexane + N,N-dimetylformamide. J. Chem. Eng. Data 48, 152–157 (2003) | pl_PL |
| dc.references | Tong-Chun, B., Jia, Y., Shi-Jun, H.: Excess molar volumes for the ternary mixture N,N-dimethylformamide + methanol + water at temperature 298.15 K. J. Chem. Eng. Data 44, 491–496 (1999) | pl_PL |
| dc.references | Akhtar, S., Faruk, A.N.M.O., Saleh, M.A.: Viscosity of aqueous solutions of formamide, N-methylformamide and N,N-dimethylformamide. Phys. Chem. Liq. 39, 383–399 (2001) | pl_PL |
| dc.references | Redlich, O., Meyer, D.M.: The molal volumes of electrolytes. Chem. Rev. 64, 221–227 (1964) | pl_PL |
| dc.references | de Oliveira, L.H., da Silva, J.M.L., Anzar, J.: Apparent and partial molar volumes at infinite dilution and solid–liquid equilibria of dibenzothiophene + alkane systems. J. Chem. Eng. Data 56, 3955–3962 (2011) | pl_PL |
| dc.references | de Visser, C., Heuvesland, W.J.M., Donn, L.A., Sosen, G.: Physical chemistry in condensed phases. J. Chem. Soc. Faraday Trans. 1 74, 1159–1169 (1978) | pl_PL |
| dc.references | Perron, G., Desnoyers, J.E.: Heat capacities and volumes of dilute aqueous solutions of 1,3-dioxane and trioxane. Can. J. Chem. 59, 2599–2600 (1981) | pl_PL |
| dc.references | Oswal, S.L., Desai, J.S., Ijardar, S.P.: Studies of partial molar volumes of alkylamine in non-electrolyte solvents: I. Alkylamines in hydrocarbons at 303.15 and 313.15 K. Thermochim. Acta 449, 73–89 (2006) | pl_PL |
| dc.references | Thakur, P.K., Patre, S., Pande, R.: Thermophysical and excess properties of hydroxamic acids in DMSO. J. Chem. Thermodyn. 58, 226–236 (2013) | pl_PL |
| dc.references | Bernal, P., McCluan, J.: Apparent molar volumes and adiabatic compressibilities of crown ethers and glymes in H2O and D2O at 25 °C. J. Solution Chem. 30, 119–131 (2001) | pl_PL |
| dc.references | Høiland, H.: In: Hinz, H.-Ju. (ed.) Thermodynamic Data for Biochemistry and Biotechnology, p. 17. Springer, Berlin (1986) | pl_PL |
| dc.references | Zielenkiewicz, W., Kulikov, O.V., Kulis-Cwikla, I.: Excess enthalpies and apparent molar volumes of aqueous solutions of crown ethers and cryptand(222) at 25 °C. J. Solution Chem. 22, 963–973 (1993) | pl_PL |
| dc.references | Sengwa, R.J., Khatri, V., Sankhla, S.: Structure and hydrogen bonding in binary mixtures of N,N-dimethyloformamide with some dipolar and protic solvents by dielectric characterization. Ind. J. Chem. 48, 512–519 (2009) | pl_PL |
| dc.references | Schmid, E.D., Brodbek, E.: Raman intensity calculations with the CNDO method. Part III: N,N-dimethylamide–water complex. Can. J. Chem. 63, 1365–1371 (1985) | pl_PL |
| dc.references | Eaton, G., Symons, M.C.R., Rastogi, P.P.: Spectroscopic studies of the solvation of amides with N–H groups. Part 1: the carbonyl group. J. Chem. Soc. Faraday Trans. 1 85, 3257–3271 (1989) | pl_PL |
| dc.references | Eberhardt, E.S., Raines, R.T.: Amide–amide and amide–water hydrogen bonds: implications for protein folding and stability. J. Am. Chem. Soc. 116, 2149–2150 (1994) | pl_PL |
| dc.references | Pikkarainen, L.: Excess enthalpies of binary solvent mixtures of methanol, ethanol and 1-propanol with formamide, N-methylformamide and N,N-dimethylformamide. Thermochim. Acta 178, 311–319 (1991) | pl_PL |
| dc.references | Assarson, P., Erich, F.R.: Properties of amides in aqueous solution. I. Viscosity and density changes of amide–water systems. An analysis of volume deficiencies of mixtures based on molecular size differences (mixing of hard spheres). J. Phys. Chem. 72, 2710–2719 (1968) | pl_PL |
| dc.references | Dawber, J.G.: Magneto–optical rotation studies of liquid mixtures. Part 5. Binary mixtures of water with dimethylsulphoxide, formamide, methylformamide, dimethylformamide and acetonitrile. J. Chem. Soc. Faraday Trans. 1 78, 1127–1130 (1982) | pl_PL |
| dc.references | García, B., Alcalde, R., Leal, J.M., Matos, J.S.: Solute–solvent interactions in amide–water mixed solvents. J. Phys. Chem. B 101, 7991–7997 (1997) | pl_PL |
| dc.references | Geller, B.E.: Svoistva sistemy dimetilformamid–voda. 1. Termokhimicheskiye issledovaniya. Zh. Fiz. Khim. (in Russian) 35, 1105–1113 (1961) | pl_PL |
| dc.references | Frank, H.S., Evans, M.W.: Free volume and entropy in condensed systems. II. Entropy in binary liquid mixtures; partial molar entropy in dilute solutions; structure and thermodynamics of aqueous electrolytes. J. Chem. Phys. 13, 507–532 (1945) | pl_PL |
| dc.references | Lipkowski, J.: Hydrphobic hydration. Ecological aspects. J. Therm. Anal. Cal. 83, 523–531 (2006) | pl_PL |
| dc.references | Jóźwiak, M., Piekarski, H.: Heat of solution of 15-crown-5 ether in the mixtures of water with DMSO, DMF, DMA and HMPA at 298.15 K. J. Mol. Liq. 81, 63–70 (1999) | pl_PL |
| dc.references | Nichols, G., Orf, J., Reiter, S.M., Chickos, J., Gokel, G.W.: The vaporization enthalpies of some crown and polyethers by correlation gas chromatography. Thermochim. Acta 346, 15–28 (2000) | pl_PL |
| dc.references | de Visser, C., Grünbauer, H.J.M., Somsen, G.: Enthalpies of solution of urea in binary mixtures of water and some amides at 25 °C. Z. Phys. Chem. Neue Fol. 97, 69–78 (1975) | pl_PL |
| dc.references | Della Gatta, G., Badea, E., Jóźwiak, M., Del Vecchio, P.: Thermodynamics of solvation of urea and some monosubstituted N-alkylureas in water at 298.15 K. J. Chem. Eng. Data 52, 419–425 (2007) | pl_PL |
| dc.references | Bernal, P., Bunn, A., Logan, J., McCluan, J.: Apparent molar volumes and adiabatic compressibilities of crown ethers and glymes in aqueous solutions at various temperatures. J. Solution Chem. 29, 651–665 (2000) | pl_PL |
| dc.contributor.authorEmail | mjozwiak@uni.lodz.pl | pl_PL |
| dc.identifier.doi | 10.1007/s10953-014-0138-7 | |
| dc.relation.volume | 43 | pl_PL |
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