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dc.contributor.authorKowalski, Konrad
dc.contributor.authorKarpowicz, Rafał
dc.contributor.authorMlostoń, Grzegorz
dc.contributor.authorMiesel, Dominique
dc.contributor.authorHildebrandt, Alexander
dc.contributor.authorLang, Heinrich
dc.contributor.authorCzerwieniec, Rafał
dc.contributor.authorTherrien, Bruno
dc.date.accessioned2015-08-28T12:31:45Z
dc.date.available2015-08-28T12:31:45Z
dc.date.issued2015-02-20
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/11089/11589
dc.description.abstractThree novel diferrocenyl complexes were prepared and characterised. 2,2-Diferrocenyl-4,5-dimethyl- 3,6-dihydro-2H-thiopyran (1, sulphide) was accessible by the hetero-Diels–Alder reaction of diferrocenyl thioketone with 2,3-dimethyl-1,3-butadiene. Stepwise oxidation of 1 gave the respective oxides 2,2- diferrocenyl-4,5-dimethyl-3,6-dihydro-2H-thiopyran-1-oxide (2, sulfoxide) and 2,2-diferrocenyl-4,5- dimethyl-3,6-dihydro-2H-thiopyran-1,1-dioxide (3, sulfone), respectively. The molecular structures of 1 and 3 in the solid state were determined by single crystal X-ray crystallography. The oxidation of sulphide 1 to sulfone 3, plays only a minor role on the overall structure of the two compounds. Electrochemical (cyclic voltammetry (= CV), square wave voltammetry (= SWV)) and spectroelectrochemical (in situ UV-Vis/NIR spectroscopy) studies were carried out. The CV and SWV measurements showed that an increase of the sulphur atom oxidation from −2 in 1 to +2 in 3 causes an anodic shift of the ferrocenylbased oxidation potentials of about 100 mV. The electrochemical oxidation of 1–3 generates mixedvalent cations 1+–3+. These monooxidised species display low-energy electronic absorption bands between 1000 and 3000 nm assigned to IVCT (= Inter-Valence Charge Transfer) electronic transitions. Accordingly, the mixed-valent cations 1+–3+ are classified as weakly coupled class II systems according to Robin and Day.pl_PL
dc.description.sponsorshipAuthors (K. K. and G. M.) thank the National Science Centre (Poland) for financial support (Project Maestro-3; Dec-2012/06/ A/ST5/00219) and R. C. thanks the German Federal Ministry of Education and Research (BMBF) for support. The support from the German Academic Exchange Service (DAAD) in the framework of the exchange program “Ostpartnerschaften” is highly appreciated.pl_PL
dc.language.isoenpl_PL
dc.publisherRoyal Society of Chemistrypl_PL
dc.relation.ispartofseriesDalton Transactions;2015
dc.rightsUznanie autorstwa 3.0 Polska*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/pl/*
dc.titleSynthesis and (spectro)electrochemistry of mixedvalent diferrocenyl–dihydrothiopyran derivativespl_PL
dc.typeArticlepl_PL
dc.page.number6268-6276pl_PL
dc.contributor.authorAffiliationKowalski Konrad, Faculty of Chemistry, Department of Organic Chemistry, University of Łódźpl_PL
dc.contributor.authorAffiliationKarpowicz Rafał, Faculty of Chemistry, Department of Organic Chemistry, University of Łódźpl_PL
dc.contributor.authorAffiliationMlostoń Grzegorz, Faculty of Chemistry, Department of Organic and Applied Chemistry, University of Łódźpl_PL
dc.contributor.authorAffiliationMiesel Dominique, Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Department of Inorganic Chemistrpl_PL
dc.contributor.authorAffiliationHildebrandt Alexander, Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Department of Inorganic Chemistrpl_PL
dc.contributor.authorAffiliationLang Heinrich, Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Department of Inorganic Chemistrpl_PL
dc.contributor.authorAffiliationCzerwieniec Rafał, Universität Regensburg, Institut für Physikalische und Theoretische Chemie,pl_PL
dc.contributor.authorAffiliationTherrien Bruno, Institute of Chemistry, University of Neuchatelpl_PL
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dc.contributor.authorEmailkondor15@wp.plpl_PL
dc.identifier.doiDOI: 10.1039/c5dt00246j
dc.relation.volume44pl_PL


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Uznanie autorstwa 3.0 Polska
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